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For detecting sulphur, Lasssaigne's solu...

For detecting sulphur, Lasssaigne's solution is treated with sodium nitroprusside solution, which contains the ion

A

`[Fe(CN)_(5)NO]^(2-)`

B

`[Fe(CN)_(5)NOS]^(4-)`

C

`[Fe(H_(2)O)_(5)NO]^(2-)`

D

`[Fe(H_(2)O)_(5)NOS]^(4-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Nitroprusside contain the complex ion
`[Fe(CN)_(5)NO]^(2-)`.
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Knowledge Check

  • Lassaigne's solution gives violet colouration with sodium nitroprusside. It indicates the presence of

    A
    nitrogen
    B
    sulphur
    C
    halogen
    D
    both N and S.
  • In Lassaigne's solution, pink/violet colouration is produced when sodium nitroprusside solution is added. It indicates the presence of:

    A
    sulphur
    B
    nitrogen
    C
    chlorine
    D
    none of these
  • In a Lassaigne's test for sulphur in the organic compound with sodium nitroprusside solution the violet colour formed is due to :

    A
    `Na_(4)[Fe(CN)_(5)NOS]`
    B
    `Na_(3)[Fe(CN)_(5)S]`
    C
    `Na_(2)[Fe(CN)_(5)NOS]`
    D
    `Na_(3)[Fe(CN)_(6)]`
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