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Nitric acid is added to sodium fusion ex...

Nitric acid is added to sodium fusion extract and the solution is boiled before adding silver nitrate for testing halogens because

A

the extract is alkaline and thus must be neutralized.

B

intric acid decomposes sodium cyanide or sodium sulphide (if present) to hydrogen cyanide and hydrogen sulphide gases, respectively.

C

nitric acid oxidizes halogen to halide ion.

D

nitric acid dissolves silver nitrate.

Text Solution

Verified by Experts

The correct Answer is:
B

`NaCN + HNO_(3) rarr HCN + NaNO_(3)`
`Na_(2)S + HNO_(3) rarr H_(2)S + NaNO_(3)`
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Why is acid added to sodium extract before adding silver nitrate for testing halogens ?

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Knowledge Check

  • Which of the following compound is added to the sodium extract before addition of silver nitrate for testing of halogens?

    A
    nitric acid
    B
    ammonia
    C
    hydrochloric acid
    D
    sodium hydroxide
  • The lassaigne's extract is boiled with dil. HNO_(3) before testing for halogens because

    A
    Silver halides are soluble in `HNO_(3)`
    B
    `Na_(2)S and NaCN` are decomposed by `HNO_(3)`
    C
    `Ag_(2)S` is soluble in `HNO_(3)`
    D
    AgCN is soluble in `HNO_(3)`
  • The Lassaigne's extract is boiled with dil. HNO_(3) before testing for halogens because

    A
    Silver halides are soluble in `HNO_(3)`
    B
    `Na_(2)S` and `NaCN` are decomposed by `HNO_(3)`
    C
    `Ag_(2)S` is soluble in `HNO_(3)`
    D
    `AgCN` is soluble in `HNO_(3)`
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