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Which of the following has highest nucle...

Which of the following has highest nucleophilicity ?

A

`F^(-)`

B

`OH^(-)`

C

`CH_(3)^(-)`

D

`NH_(2)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
C

Nucleophilicity is directly related to the basic strength if nucleophilic atoms belong to the same period of the periodic table.
Order of basic strength of conjugates acids:
`HF gt H_(2)O gt NH_(3) gt CH_(4)`
Order of basic sterngth of conjugate bases:
`CH_(3)^(-) gt NH_(2)^(-)gt OH^(-) gtF^(-)`
Thus, order of nucleophilicity is as follows:
`CH_(3)^(-) gt NH_(2)^(-) gt OH^(-) gt F^(-)`
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