Home
Class 11
CHEMISTRY
In which of the following compounds, doe...

In which of the following compounds, does the substituent not exert its resonance effect?

A

`C_(6)H_(5)overset(+)(N)H_(3)`

B

`C_(6)H_(5)Cl`

C

`C_(6)H_(5)OH`

D

`C_(6)H_(5)NH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

`overset(+)NH_(3)` group exert only `-I` effect on account of higher electronegativity of `N` atom than the `C` atom of benzene ring and due to ists `+ve` charge. It is not able to exert `+R` effect as there is no long pair of electrons. It fails to exert `-R` effect beacuse `N` is not `pi` bonded to more electronegative atom.
Promotional Banner

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 8|9 Videos
  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 9|6 Videos
  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 6|10 Videos
  • EQUILIBRIUM

    R SHARMA|Exercise ARCHIVES|69 Videos
  • ISOMERISM

    R SHARMA|Exercise Archives|11 Videos

Similar Questions

Explore conceptually related problems

In which of the following molecules, the substituent does not exertis resonance effect ?

Which of the following compounds does not exhibit resonance?

Which of the following compounds does not show electromeric effect

In which of the following molecule/ions are the inductive effect, resonance effect, and hyperconjugation all operating simultaneously?

In which of the following compound, chlorinie exerts the maximum number of electronic effects ?

Which of the following compound is not resonance stabilized ?

Which of the following compound will not show steric inhibition of resonance?