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Which of the following alkyl halides is ...

Which of the following alkyl halides is not suitable for reactions with lithium dialkylcuprate in the Corey-House synthesis?

A

`(CH_(3))_(3)CBr`

B

`C_(2)H_(5)Br`

C

`CH_(3)Br`

D

`CH_(3)CH_(2)CH_(2)I`

Text Solution

Verified by Experts

The correct Answer is:
A
`R_(2)CuLi+R'-XrarrR-R'+RCu+LiX`
To get a good yield of the alkane, a primary alkyl halide,or a secondary cycloalkyl halide.
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