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Consider the reaction RH+(CH(3))(3)C-O...

Consider the reaction
`RH+(CH_(3))_(3)C-O-Cloverset("Heat")rarr`
The expected major products are

A

`(CH_(3))_(3)COH` and `RCl`

B

`ROCl` and `(CH_(3))_(3)CH`

C

`ROH` and `(CH_(3))_(3)C CI`

D

`(CH_(3))_(3)COR` and `HCl`

Text Solution

Verified by Experts

The correct Answer is:
A

Alkanes are monochlorinated with `t`-butyl hypochlorite, `t-BuOCl`
Initiation: Homolysis of the hypochlorite

Propagation steps
(a) `t-Buoverset(.)O+R-Hrarrt-BuOH+R^(.)`
(b) `R^(.)+t-BuOClrarrRCl+t-BuO^(.)`
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