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Convert acetic acid into benzene. Stra...

Convert acetic acid into benzene.
Strategy: There is no fixed strategy for conversions but it is best to work backwards. Remember, benzene can be obtained from acetylene, now think how to get acetylene from acetic acid.

Text Solution

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`CH_3COOHoverset(NaOH(eq))toCH_3COONaunderset(Delta)overset("sodalime")toCH_4underset(hv)overset(Cl_2)toCH_3Clunderset("dry ether")overset(Na)toCH_3-CH_3underset(hv)overset(Cl_2)toCH_3CH_2-Clunderset(KOH)overset(Alc)toCH_2=CH_2`
`underset(C Cl_4)overset(Br_(2))tounderset(CH_(2)Br)underset(|)(C)H_(2)Brunderset((2)" HA")overset((1)" "NaNH_(2),Delta)toCH-=CHunderset("iron tube")overset("Red hot")to`
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  3. From which one of the following can both ethylene and acetylene be pre...

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  4. The treatment of CH(3)MgX with CH-=CH produces

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  5. The hydrocarbon which can react with sodium in liquid ammonia is

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  6. Base strength of (i) CH3CH2^(-) (ii) CH2=CH^(-) (iii) CH-=C^(-)

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  7. The product C is CH(3).CH(2).C-=CH+HCl rarrBoverset(HI)rarrC

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  8. Under which of the following conditions does the reaction HC-=CH+CH2OH...

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  9. Which of the following reactions will yeild 2,2-dibromo propane?

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  10. The reaction of acetylene and propyne with HgSO4 in the presence of H2...

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  11. An organic compound decolorizes Br2 water and also gives red ppt. with...

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  12. Ethene and ethyne can be distinguished by

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  13. In the following sequency of reactions CH3CH2Broverset(KOH)toXoverse...

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  14. HC-=CH reacts with acetic acid in the presence of Hg^(2g+) ions to giv...

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  15. Aoverset(H(2)//"Lindlar's catalyst")larrCH3C-=C CH(3)overset(Na//Liq" ...

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  16. In the reaction CH3C-=C CH3underset((Zn)/(H2O))overset(R)toCH3COCOCH...

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  17. The products of the following reactions CH3C-=C CH2CH3underset("oxid...

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  18. Propyne when passed through a hot iron tube at 400^@C produces

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  19. H--=-Hoverset((i)O3)underset((ii)(H2O)//(Zn))rarr(A)overset(Zn//CH3COO...

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  20. Which of these will not react with acetylene?

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  21. When CH3CH2CHCl2 is treated with NaNH2, the product formed is

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