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1,2-Dichloroethane is heated with KOH (1...

1,2-Dichloroethane is heated with KOH (1 mol) in ethanol The major product formed is

A

ethylene glycol

B

acetylene

C

2-chloroethanol

D

vinyl chloride

Text Solution

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The correct Answer is:
To solve the problem of what major product is formed when 1,2-Dichloroethane is heated with KOH in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 1,2-Dichloroethane (C2H4Cl2), which has the structure: ``` Cl-CH2-CH(Cl)-CH3 ``` 2. **Understand the Reaction Conditions**: - KOH is a strong base and is used in alcoholic solution (ethanol). This indicates that we are likely to undergo an elimination reaction (dehydrohalogenation) rather than a substitution reaction. 3. **Determine the Type of Reaction**: - Since we are using KOH in ethanol, we expect an elimination reaction where KOH will remove a hydrogen atom and a chlorine atom from the molecule. 4. **Select the Chlorine Atom to Remove**: - We have two chlorine atoms in 1,2-Dichloroethane. Since KOH is in a 1:1 molar ratio, it will remove one of the chlorine atoms. We can choose either chlorine atom for removal, but typically, the more accessible one is removed first. 5. **Removing a Chlorine Atom**: - Let's say we remove one chlorine atom from the first carbon (C1). The structure after removing Cl from C1 will be: ``` H2C=CH(Cl) ``` 6. **Removing a Hydrogen Atom**: - Now, we need to remove a hydrogen atom from the adjacent carbon (C2) to form a double bond. The KOH will abstract a hydrogen atom from C2, leading to the formation of a double bond between C1 and C2. 7. **Final Product Formation**: - After removing the hydrogen and chlorine, the resulting compound will be: ``` H2C=CH-Cl ``` - This compound is known as Vinyl Chloride. 8. **Conclusion**: - The major product formed from the reaction of 1,2-Dichloroethane with KOH in ethanol is Vinyl Chloride (C2H3Cl). ### Final Answer: The major product formed is **Vinyl Chloride (C2H3Cl)**. ---

To solve the problem of what major product is formed when 1,2-Dichloroethane is heated with KOH in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 1,2-Dichloroethane (C2H4Cl2), which has the structure: ``` Cl-CH2-CH(Cl)-CH3 ...
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