Home
Class 11
CHEMISTRY
CH3C-=C CH3underset(CaCO3 and BaSO4)over...

`CH_3C-=C CH_3underset(CaCO_3 and BaSO_4)overset((H_2)/(Pd))to p` Identifty the product quinoline.

A

cis-But-2-ene

B

trans-But-2-ene

C

An equimolar mixture of (1) and (2)

D

unequal amounts of both (1) and (2)

Text Solution

Verified by Experts

The correct Answer is:
A

`H_2` is adsorbed on the metallic surface, being converted to reactive individual H atoms, the alkyne is also adsorbed, probably through the formation of a `pi` complex the individual H atoms transfer stepwise to the open face of the `pi` bond and the addition is sys. The reduced alkyne then leaves the surface.
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

CH_(3)-C-=C-CH_(3)underset(Pd-BaSO_(4))overset(H_(2))rarr (A) underset(C Cl_(4))overset(Br_(2))rarr(B)

CH_(3)-overset(CH_(3))overset(|)(CH)-CH_(2)-CH_(2)underset(O)underset(||)C-CH_(3)^(+)overset(H_(2)//Pd//C)to No. of stereoisomerism.

CH_(3)-C-=C-CH_(3)underset(Pd-BaSO_(4))overset(H_(2))rarr(A) overset("cold. "KMnO_(4))rarr(B) . Compound (B) is :

H_(3)C-CH_(2)-underset(O)underset(||)(C)-CH_(3)underset(D_(2)O)overset(NaBH_(4))to Product ?

CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)-OH overset(conc. H_(2)SO_(4))underset(Delta)rarrP The product "P" is

R SHARMA-ALKYNES-Question Bank
  1. 2,3-dibromobutane is treated with sodium amide (excess) in liquid ammo...

    Text Solution

    |

  2. Stilbene (C6H6=CHC6H5) reacts with (Br2)/(CCl4) and the resulting prod...

    Text Solution

    |

  3. CH3C-=C CH3underset(CaCO3 and BaSO4)overset((H2)/(Pd))to p Identifty t...

    Text Solution

    |

  4. Which of the followig reagents may be used to distinguish between but-...

    Text Solution

    |

  5. The total number of isomers possible for the formula C3H4 is

    Text Solution

    |

  6. Chloroethene is treated with sodium amide in liquid ammonia. The major...

    Text Solution

    |

  7. Al4C3,Mg2C3 and CaC2 are hydrolyzed separately. The hydrocarbons forme...

    Text Solution

    |

  8. CH-=CHunderset(Hg^(2+))overset(CH3CO2H(2mol))toAoverset(Heat)toB The f...

    Text Solution

    |

  9. Which of the following is least preffered to make higher alkynes fom s...

    Text Solution

    |

  10. HC-=Chunderset(1mol)overset(NaNH2)toAunderset((2)H2O)overset((1)H2CO)t...

    Text Solution

    |

  11. Br2CHCHBr2underset(C2H5OH,Delta)overset(Zn(1mol))toP Identify the ma...

    Text Solution

    |

  12. HC-=Chunderset(1mol)overset(Na)toAoverset(D2O)toB Identify the final...

    Text Solution

    |

  13. A hydrocarbon (A) reacts with sodium amide and then with ethylbromide ...

    Text Solution

    |

  14. HC-=Chunderset(NaCN)overset(HCN)to p Identify the product p

    Text Solution

    |

  15. propyne undergoes cycloaddition reaction in the presence of Ziegler-Na...

    Text Solution

    |

  16. Orlon is a synthetic fiber obtained by the polymerization of a monomer...

    Text Solution

    |

  17. The total number of compounds than have the same general formula as th...

    Text Solution

    |

  18. When methane gas is heated at 1500^(@)C for a very short time in open ...

    Text Solution

    |

  19. Which of the following acts as a good catalyst in the process of trime...

    Text Solution

    |

  20. Acetylene underset(O2)overset(Cu^(2+)to The product formed in the reac...

    Text Solution

    |