Home
Class 12
CHEMISTRY
which of the following statement is corr...

which of the following statement is correct for the `NaCl` lattice?

A

An `Na^(+)` ion is placed at a distance of `(1)/(sqrt(2))a` directly above each `Cl^(-)` (where a is the cube unit cell edge length).

B

An `Na^(+)` ion is placed at a distance of `(1)/(2sqrt(2))` a directly above each `Cl^(-)` ion.

C

An `Na^(+)` ions is placed at a distance of `(1)/(6)a` directly above each `Cl^(-)` ion

D

An `Na^(+)` ion is placed at a distance of `(1)/(2)a` directly above each `Cl^(-)`.

Text Solution

Verified by Experts

The correct Answer is:
4

Simple ionic solids such a `NaCl` are like metals in that the individual ions are spheres that pack together in a regular way.However they differ from metals in that the spheres are not all the same size-anions are generally larger than cations . As a result ,ionic soilds adopt a variety fo different unit cells depending on the size and charge of the ions.`NaCl` has a face -centered cubic unit cell in which is the larger `CI^(-)` anions occupy corners and face centres , while the smaller `Na^(+)` cations fit into the octahedral holes between adjacent `CI^(-)` ions.
Promotional Banner

Topper's Solved these Questions

R SHARMA-SOLID STATE-Follow Test 5
  1. The coordination number of each atom in body centered cubic unit cell...

    Text Solution

    |

  2. Potassium crystallizes with a

    Text Solution

    |

  3. In a two -dimensional hexagonal close-packed layer. (i) each sphere ...

    Text Solution

    |

  4. Hexagonal closet packed arrangement of equal -sized spheres is describ...

    Text Solution

    |

  5. In hexagonal closest-packed arrangement each spher has a coordinationn...

    Text Solution

    |

  6. Which of the following noble gases crystallizes in hcp structure?

    Text Solution

    |

  7. The staking pattern of cubic closet packed arrangement is

    Text Solution

    |

  8. The coordination number of the fcc structure for metals is

    Text Solution

    |

  9. Which of the following metals does not have and fcc structure?

    Text Solution

    |

  10. Which of the following statement is correct for a closet packed struct...

    Text Solution

    |

  11. The ratio of the size of the central atom to the size of the coordanat...

    Text Solution

    |

  12. If in a closest packed arrangement r is the radius of the sphere respr...

    Text Solution

    |

  13. In a crystalline solid, anions B are arranged in a ccp. Cations A are ...

    Text Solution

    |

  14. Barium titanate crystallizes in perovskite structure (ABO(3)) which is...

    Text Solution

    |

  15. In an ionic compound, oxide ions have ccp arrangement Cations A are pr...

    Text Solution

    |

  16. which of the following statement is correct for the NaCl lattice?

    Text Solution

    |

  17. In CsCl the number of formula units per unit cell is

    Text Solution

    |

  18. Which of the following is polymorphic?

    Text Solution

    |

  19. The ZnS structure can be obtained from the

    Text Solution

    |

  20. In calcium fluoride (CaF(2)), the coordinate number of each Ca^(2+) io...

    Text Solution

    |