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Which of the following lanthanoid ions i...

Which of the following lanthanoid ions is diamagnetic? (Atomic number of `Ce=58,Sm=62,Eu=63,Yb=70`]

A

`Sm^(2+)`

B

`Eu^(2+)`

C

`Yb^(2+)`

D

`Ce^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

`Ce (4f^(1) 5d^(1) 6s^(2)) rarr Ce^(2+) (4f^(1) 5d^(1))`
`Sm (4f^(6) 6s^(2)) rarr Sm^(2+) (4f^(6))`
`Eu(4f^(7) 6s^(2)) rarr Eu^(2+) (4f^(7))`
`Yb (4f^(14) 6s^(2)) rarr Yb^(2+) (4f^(14))`
`Yb^(2+)` is dimagetic as there is no unpaired electron due to completely full 4f subshell.
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