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Which one of the following forms a colou...

Which one of the following forms a colourless solution in aqueous medium ?
(Atomic number : `Sc =21, Ti = 22, V = 23`, and `Cr = 24`)

A

`V^(3+)`

B

`Cr^(3+)`

C

`Ti^(3+)`

D

`Sc^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
D

Colour is usually due to d-d trnsition :
`V (3d^(3) 4s^(2)) implies V^(3+) (3d^(2))` : coloured
`Cr (3d^(5) 4s^(1)) implies Cr^(3+) (3d^(3))` : colored
`Ti (3d^(2) 4s^(2)) implies Ti^(3+) (3d^(1))` : coloured
`Sc (3d^(1) 4s^(2)) implies Sc^(3+) (3d^(0))` : colourless.
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