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The coordination number of cobalt in tri...

The coordination number of cobalt in tris(ethylendiamine) cobalt(III) ion, `[Co(en)_(3)]^(3+)` , is

A

3

B

6

C

9

D

5

Text Solution

Verified by Experts

The correct Answer is:
B

The number of ligand donor atoms to which the central metal atom/ion is directly bonded in a complex enity is called the coordination number of the metal. In the complex ion, `[Co(en_(3))^(3+)]` , the coordination number (CN) of Co is 6 because en (ethane -1,2-diamine) is a bidenate ligand and hence provides two donor atoms.
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Knowledge Check

  • Tris (ethylenediamine) cobalt (III) cation, [Co(en)_3]^(3+) , can have

    A
    (a) three stereoisomers, all chiral and optically active
    B
    (b) two chiral stereoisomers (enantiomers) and one achiral
    C
    (c) three stereisomers, all archiral
    D
    (d) two stereoisomers, both achiral
  • The formula of complex tris (ethylenediamine) cobalt (III) sulphate is :

    A
    `[Ce(e n)_(2)SO_(4)]`
    B
    `[Co(e n)_(3)SO_(4)]`
    C
    `[Co (e n)_(3)]_(2) SO_(4)`
    D
    `[Co (e n)_(3)]_(2) (SO_(4))_(3)`
  • The formula of complex tris ( ethylenediamine ) cobalt (III) sulphate is

    A
    `[Co(en)_(2)SO_(4)]`
    B
    `[Co(en)_(3)SO_(4)]`
    C
    `[Co(en)_(3)]_(2)SO_(4)`
    D
    `[Co(en)_(3)]_(2)(SO_(4))_(3)`
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