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The hybridization involved in complex [N...

The hybridization involved in complex `[Ni(CN)_(4)]^(2-)` is `(At. No . Ni = 28)`

A

`d^(2)sp^(2)`

B

`d^(2)sp^(3)`

C

`dsp^(2)`

D

`sp^(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

Here nickel is in `+2` oxidation state has the electronnc configuration `3d^(8)` . Since `CN^(-)` ion is a strong field lignd, the electronic configuration is reshuffled to pair up all the electrons so as to provide one empty orbital for `dsp^(2)` hybrization.


`[Ni(CN)_(4)]^(2-)`

Four pairs of form `4CN^(-)` ligands electrons
Each of the hybridised orbitals receives a pair of electrons form a cyanide ion.
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