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[Co(HN(3))(6)][Cr(CN)(6)] and [Cr(NH(3))...

`[Co(HN_(3))_(6)][Cr(CN)_(6)]` and `[Cr(NH_(3))_(6)][Co(CN)_(6)]` are .

A

Geometrical isomerism

B

Linkage isomerism

C

Ionization isomerism

D

coordination isomerism

Text Solution

Verified by Experts

The correct Answer is:
D
Coordination isomerism is shown by those ionic coordination copmpounds in which both cation as well as anion are complexes (coordination entites) and ligands interchange their positions between the two complex ions.
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Which isomerism is exhibited by [Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] ?

The complexes [Co(NH_(3))_(6)][C(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] are the examples of which type of isomerism ?

How can be the following pair of isomers be distinguished from one another I [Co(NH_(3))_(6)][Cr(NO_(2))_(6)] and (II) [Cr(NH_(3))_(6)][Co(No_(2))_(6)] I [Cr(NH_(3))_(6)[Cr(No_(2))_(6)] and (II) [Cr(NH_(3))_(4)(No_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)] .

Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)

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