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Of the following complex ions, which is ...

Of the following complex ions, which is diamagnetic in natures?

A

`[CoF_(3)]^(3-)`

B

`[NiCI_(4)]^(2-)`

C

`[Ni(CN)_(4)]^(2-)`

D

`[CuCI_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[CoF_(6)]^(3-)` , no rerrangement as `F^(-)` is a weak field ligand

`[NiC1_(4)]^(2-)` , no rearrangement as `C1^(-)` is a weak field ligand

`[Ni(CN)_(4)]^(2-)` , rearrnangement as `CN^(-)` is a strong field ligand

`[CuC1_(4)]^(2-)` , no rearrangement as `C1^(-)` is a weak field ligand
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  9. Which of the following does not show optical isomerism ?

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  13. In which of the following coordination entites the magnitude of Delta(...

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  14. The d electron congfiguration of Cr^(2+) , Mn^(2+) , Fe^(2+) and Ni^(2...

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  15. Which of the following will give a pair of enontiomorphs ? en = NH(2...

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  16. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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  17. [Co(NH(3))(4)(NO(2))(2)]CI exhibits

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  18. Which one of the following is expected to exhibit optical isomerism (e...

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  19. Which one of the following is an inner orbital complex as well as diam...

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