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Consider the reaction 1/2H(2)(g)+AgCI(...

Consider the reaction
`1/2H_(2)(g)+AgCI(s)rarrH^(+)(aq)+CI^(-)(aq)+Ag(s)`
In which of the following galvanic ell the abvoe reaction occurs ?

A

`Ag|AgCI(s)|KCI(aq)||AgNO_(3)(Aq)|Ag(s)`

B

`Pt|H_(2)(g)|HCI(Aq)||AgNO_(3)(aq)||Ag(s)`

C

`Pt|H_(2)(g)|HCI(aq)||AgCI(s)||Ag(s)`

D

`Pt|H_(2)(g)|KCI(aq)||AgCI(s)||Ag(s)`

Text Solution

Verified by Experts

The correct Answer is:
D
`H_(2)` undergoes oxidation and `AgCI(ag^(+)`
undergoes reduction therefore cell may be represent as
`Pt|H_(2)(g)|HCI(aq)||AgCI(s)||Ag(s)`
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