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Which of the following is added to chlor...

Which of the following is added to chloroform to slow down its aerial oxidationin presence of light ?

A

Carbonyl chloride

B

Ethyl alcohol

C

Sodium hydroxide

D

Nitric acid

Text Solution

Verified by Experts

The correct Answer is:
B

Chloroform is oxidised to a poisonous gas by aerial oxidation.
`CHCl_(3)+[O] rarr underset("Phosgene")(COCl_(2))+HCl`
Ethyl alcohol is used as a negative catalyst for the aerial oxidation of chloroform is presence of light. It converts `COCl_(2)` to non-poisonous diethyl carbonate.
`COCl_(2)+2C_(2)H_(5)OH rarr O=C(OC_(2)H_(5))+2HCl`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALKYL HALIDE-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
  1. C(2)H(5)Cl overset("Moist")underset(Ag(2)O)(to) (A) overset(AI(2)O(3))...

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  2. The major product formed in the following reaction is CH(3)CH(Cl)CH(2)...

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  3. Which of the following is added to chloroform to slow down its aerial ...

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  4. The raction of toluene with CI(2) in presence of FeCI(3) gives X and r...

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  5. Chlorobenzene reacts with Mg in dry ether to give a compound A, which ...

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  6. Chlorobenzene is prepared commercially by

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  7. Which of the following compounds has the highest boiling point ?

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  8. Tertiary alkyl halide are practially inert to substitution by SN^(2) ...

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  9. The position of Br in the compound in CH(3)=CHC(Br)(CH(3))(2) can be c...

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  10. The IUPAC name of, Compound is

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  11. For the above reaction I. X = Cl, ortho and para-isomers can be sepa...

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  12. Alkyl halides are prepared from alcohols by treating with

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  13. Arrange the following compounds in the increasing order of their densi...

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  14. The above reaction follows

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  15. 2,2 -dichlorobutane on boiling with queous KOH gives

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  16. Toluene reacts with excess of Cl(2) in the presence of sunlight to giv...

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  17. The order of reactivities of the following alky halides for an S(N)2 r...

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  18. The reaction of ethyl bromide with silver cyanide results in the forma...

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  19. the order of reactivity of alkyl halides depends upon:

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  20. Which of the following is Wurtz-Fitting reaction?

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