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The raction of toluene with CI(2) in pre...

The raction of toluene with `CI_(2)` in presence of `FeCI_(3)` gives `X` and reaction in presence of light gives `Y` Thus `X` and `Y` are .

A

X = benzyl chloride, Y = m-chlorotoluene

B

X = benzal chloride, Y = o-chlorotoluene

C

X = m-chlorotoluene, Y = p-chlorotoluene

D

X = o and p-chlorotoluene,
Y = trichloromethyl benzene

Text Solution

Verified by Experts

The correct Answer is:
D

`Cl_(2)` in presence of `FeCl_(3)` undergoes ring substitution and `Cl_(2)` in presence of light undergoes side chain substitution.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALKYL HALIDE-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
  1. The major product formed in the following reaction is CH(3)CH(Cl)CH(2)...

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  2. Which of the following is added to chloroform to slow down its aerial ...

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  3. The raction of toluene with CI(2) in presence of FeCI(3) gives X and r...

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  4. Chlorobenzene reacts with Mg in dry ether to give a compound A, which ...

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  5. Chlorobenzene is prepared commercially by

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  6. Which of the following compounds has the highest boiling point ?

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  7. Tertiary alkyl halide are practially inert to substitution by SN^(2) ...

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  8. The position of Br in the compound in CH(3)=CHC(Br)(CH(3))(2) can be c...

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  9. The IUPAC name of, Compound is

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  10. For the above reaction I. X = Cl, ortho and para-isomers can be sepa...

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  11. Alkyl halides are prepared from alcohols by treating with

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  12. Arrange the following compounds in the increasing order of their densi...

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  13. The above reaction follows

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  14. 2,2 -dichlorobutane on boiling with queous KOH gives

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  15. Toluene reacts with excess of Cl(2) in the presence of sunlight to giv...

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  16. The order of reactivities of the following alky halides for an S(N)2 r...

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  17. The reaction of ethyl bromide with silver cyanide results in the forma...

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  18. the order of reactivity of alkyl halides depends upon:

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  19. Which of the following is Wurtz-Fitting reaction?

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  20. 'A' is formed when benzene reacts with …………. In presence of AlCl(3)

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