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Tertiary alkyl halide are practially in...

Tertiary alkyl halide are practially inert to substitution by `SN^(2)` mechanism because of-

A

steric hindrance

B

inductive effect

C

instability

D

insolubility

Text Solution

Verified by Experts

The correct Answer is:
A

In `S_(N)2` reaction, nucleophile and alkyl halide react in one step.

Thus, tertiary carbon is under steric hndrance due to presence of three bulky alkyl groups thus reaction does not take place unit `(C-Br)` bond breaks
`R-overset(R)overset(|)underset(R)underset(|)C-Br overset("Slow")rarr R-overset(R)overset(|)underset(R)underset(|)(C^(o+))+Br^(-)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALKYL HALIDE-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
  1. Chlorobenzene is prepared commercially by

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  2. Which of the following compounds has the highest boiling point ?

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  3. Tertiary alkyl halide are practially inert to substitution by SN^(2) ...

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  4. The position of Br in the compound in CH(3)=CHC(Br)(CH(3))(2) can be c...

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  5. The IUPAC name of, Compound is

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  6. For the above reaction I. X = Cl, ortho and para-isomers can be sepa...

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  7. Alkyl halides are prepared from alcohols by treating with

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  8. Arrange the following compounds in the increasing order of their densi...

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  9. The above reaction follows

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  10. 2,2 -dichlorobutane on boiling with queous KOH gives

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  11. Toluene reacts with excess of Cl(2) in the presence of sunlight to giv...

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  12. The order of reactivities of the following alky halides for an S(N)2 r...

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  13. The reaction of ethyl bromide with silver cyanide results in the forma...

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  14. the order of reactivity of alkyl halides depends upon:

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  15. Which of the following is Wurtz-Fitting reaction?

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  16. 'A' is formed when benzene reacts with …………. In presence of AlCl(3)

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  17. In S(N)2 reactions, the correct order of reactivity for the following ...

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  18. Four compounds, Toluene (I), o-dichlorobenzene (II), m-dichlorobenzene...

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  19. 2-bromopentane with alcoholic KOH yields a mixture of three alkenes. W...

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  20. Compound (A) ,C(8)H(9)Br gives a white precipitate when warmed with a...

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