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If the dissociation constants of two wea...

If the dissociation constants of two weak acids `HA_(1)` and `HA_(2)` are `K_(1)` and `K_(2)`, then the relative strengths of `HA_(1)` and `HA_(2)` are given by

A

`sqrt(K_(2)//K_(1))`

B

`sqrt(K_(1)//K_(2))`

C

`K_(2)//K_(1)`

D

`K_(1)//K_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

We can compare the strengths of acids in terms of their degrees of ionization provided the acids are the same concentration.
`K_(1)=Calpha_(1)^(2)`
`K_(1)=Calpha_(2)^(2)`
Taking the ration, we get
`(K_(1))/(K_(2))=(alpha_(1)^(2))/(alpha_(2)^(2))`
or `(alpha_(1))/(alpha_(2))=sqrt(K_(1))/(K_(2))`
where the degres of ionization of two weak acids are `alpha_(1)` and `alpha_(2)` respectively.
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