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The compound CH(3)COCH(2)COOC(2)H(5) is ...

The compound `CH_(3)COCH_(2)COOC_(2)H_(5)` is treated with `LiAlH_(4)` in dry ether. The product formed is

A

`CH_(3)CH_(2)CH_(2)COOC_(2)H_(5)`

B

`CH_(3)CHOHCH_(2)CO_(2)C_(2)H_(5)`

C

`CH_(3)CHOHCH_(2)OH`

D

`CH_(3)COCH_(2)CH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the compound `CH3COCH2COOC2H5` and determine what happens when it is treated with `LiAlH4` in dry ether. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: The compound `CH3COCH2COOC2H5` contains: - A ketone group (`CH3CO-`). - An ester group (`-COOC2H5`). 2. **Understand the Reducing Agent**: `LiAlH4` (Lithium Aluminium Hydride) is a strong reducing agent that can reduce: - Aldehydes to primary alcohols. - Ketones to secondary alcohols. - Esters to alcohols. 3. **Reduction of the Ketone**: The ketone part of the compound is `CH3COCH2-`. When treated with `LiAlH4`, it will be reduced to a secondary alcohol: - `CH3COCH2-` becomes `CH3C(OH)CH2-`. 4. **Reduction of the Ester**: The ester part of the compound is `-COOC2H5`. When treated with `LiAlH4`, it will be reduced to an alcohol: - `-COOC2H5` becomes `-C(OH)C2H5`. 5. **Combine the Results**: After the reduction of both functional groups, we combine the results: - From the ketone: `CH3C(OH)CH2-`. - From the ester: `-C(OH)C2H5`. Thus, the final product is: - `CH3C(OH)CH2C(OH)C2H5`. 6. **Final Structure**: The final structure can be represented as: - `CH3C(OH)CH2C(OH)C2H5`, which is a compound with two hydroxyl (-OH) groups. ### Final Answer: The product formed is `CH3C(OH)CH2C(OH)C2H5`.

To solve the question, we need to analyze the compound `CH3COCH2COOC2H5` and determine what happens when it is treated with `LiAlH4` in dry ether. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: The compound `CH3COCH2COOC2H5` contains: - A ketone group (`CH3CO-`). - An ester group (`-COOC2H5`). ...
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R SHARMA-ALCOHOL, PHENOL AND ETHERS-Follow -Up Test -3
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  15. The maximum number of moles of carbonyl compound (aldehyde or ketone) ...

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