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Alcohols have lower boiling points than ...

Alcohols have lower boiling points than carboxylic acids of comparable molecular mass because

A

carboxylic acids show resonance but alcohols do not

B

carboxylic acids form intermolecular bonds but alcohols do not

C

intermolecular hydrogen bonding in carboxylic acids is stronger than that in alcohols

D

alcohols form intermolecular hydrogen bonds but carboxylic acids do not

Text Solution

Verified by Experts

The correct Answer is:
C

Due to strong negative inductive effect of carbonyl group , the hydrogen (of `OH` groupis carboxylic acid) is more positive to form relatively strong hydrogen bond with oxygen of other molecule.
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Assertion(A) In alcohols, the boiling point decreases with decrease in the branching of the carbon chain. Reason(R ) Alcohols have higher boiling point than haloalkanes of comparable molecular mass.

Why do alcohols have higher boiling points thann haloalkanes of comparable molecular mass?

Knowledge Check

  • Assertion: Alcohols have higher boiling points than ethers of comparable molecular masses. Reason: Alcohols and ethers are isomeric in nature.

    A
    If both assertion and reason are true, and reason is the true explanation of the assertion.
    B
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  • Assertion : Alcohols have higher boiling points than ethers of comparable moleucular masses. Reason : Alcohols and ethers are isomeric in nature.

    A
    Both A and B are true and R is the correct explanation of A.
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    A is False but R is True.
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  • Assertion : Alcohols are more boinling than aldehyes of comparable molecular masses. Reason : Stric hindrance is more than in acetaldehyde.

    A
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    Assertion: Alcohols have higher boiling points than ethers of comparable molecular masses. Reason: Alcohols and ethers are isomerism in nature.

    Why do carboxylic acids have higher boiling points than alcohol aof comparable molecular mass?

    Explain giving reasons each of the following : (i) Chloroacetic acid has lower pK_(a) value than acetic acid (ii) Carboxylic acids have higher boiling points than alcohols of comparable molecular masses (iii) Electrophilic substiution in benzoic acid takes place at the meta position.

    Why do alcohols have higher boiling points than haloalkanes of the same molecular mass?

    The high boiling points of carboxylic acids are due to