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Phenol reacts with benzoyl chloride in t...

Phenol reacts with benzoyl chloride in the presence of dilute `NaOH` to form

A

diphenyl ether

B

acetophenone

C

`alpha-`hydroxybenzophenone

D

Phenyl benzoate

Text Solution

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The correct Answer is:
To solve the problem of how phenol reacts with benzoyl chloride in the presence of dilute NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol (C6H5OH) and benzoyl chloride (C6H5COCl). 2. **Understand the Role of Dilute NaOH**: - Dilute NaOH acts as a base that helps deprotonate phenol, making it a better nucleophile. This allows it to attack the carbonyl carbon of benzoyl chloride. 3. **Draw the Structure of Phenol**: - Phenol can be represented as: ``` OH | C6H5 - C6H5 ``` 4. **Draw the Structure of Benzoyl Chloride**: - Benzoyl chloride can be represented as: ``` O || C6H5 - C - Cl ``` 5. **Nucleophilic Attack**: - The oxygen atom of the phenol (which is now negatively charged after deprotonation) attacks the carbonyl carbon of benzoyl chloride, leading to the formation of a tetrahedral intermediate. 6. **Elimination of HCl**: - The tetrahedral intermediate collapses, resulting in the elimination of HCl (hydrochloric acid) and forming the ester. 7. **Formation of Phenyl Benzoate**: - The final product of this reaction is phenyl benzoate, which can be represented as: ``` O || C6H5 - C - O - C6H5 ``` 8. **Conclusion**: - Therefore, the reaction of phenol with benzoyl chloride in the presence of dilute NaOH yields phenyl benzoate. ### Final Answer: The product formed is **phenyl benzoate**. ---

To solve the problem of how phenol reacts with benzoyl chloride in the presence of dilute NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol (C6H5OH) and benzoyl chloride (C6H5COCl). 2. **Understand the Role of Dilute NaOH**: ...
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Knowledge Check

  • Benozylation of primary and secondary amines with benzoy1 chloride in the presence of dilute NaOH to form amides is known as .

    A
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    C
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