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Which of the following reagents can dist...

Which of the following reagents can distinguish between `t-`butyl alcohol and `n-`butyl alcohol?

A

sodium

B

`ZnCl_(2) and Conc. HCl`

C

`AgNO_(3) and NH_(4)^(+)OH^(-)`

D

`CuCl_(2) and NH_(4)^(+)OH^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B

The difference in reactivity of three classes of alcohols with `HCl` distinguishes them from one another (Lucas test). Alcohols are soluble in Lucas reagent (conc. HCl and anhydrous `ZnCl_(2))` while their halides are immicible and produce turbidity is produced immediately as they form the halides easily. primary alcohols (such as `n-`butyl alcohol), do not produce turbidity at room temperature.
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