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Which one of the following statements fo...

Which one of the following statements for the order of a reaction is incorrect ?

A

Order of reaction is always a whole number

B

Order can be determined only experimentally

C

Order is not influenced by stoichiometric coefficients of the reactants.

D

Order of reaction is sum of powers to the concentration terms of reactants to express the rate of reaction

Text Solution

Verified by Experts

The correct Answer is:
A

For the general reaction
`v_(A)A+V_(B)B+...rarrv_(L)L+v_(M)M...`
If the experimentally determined rate law is given by the equation:
`Rate=k[A]^(a)[B]?^(b)` ...
then we say that the reaction is of `a^(th)` order in `A` and of `b^(th)` order in `B` and the overall order of the reaction is the sum of the exponents of concentrations of all the reactants in the rate equation.
Order of a reaction with respect to a reactant can be `0,1,2,3,` and even a fraction or negative.
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