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The unit of rate constant for a zero ord...

The unit of rate constant for a zero order reaction is `s^(-1)`.

A

`s^(-1)`

B

`mol L^(-1)s^(-1)`

C

`L mol^(-1)s^(-1)`

D

`L^(2)mol^(-2)s^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

For a general reaction
`aA+bBrarrcC+dD`
rate `=[A]^(x)[B]^(y)`
where `x+y=n=`overall order of the reaction
`K=(Rate)/([A]^(x)[B]^(y))`
`=("Concentration")/(time)xx(1)/(("concentration")^(n))`
Taking unit of concentration, `molL^(-1)` and time, `s` , the unit of rate constant for a zero-order reaction `(n=0)` is
`(molL^(-1))/(2)xx(1)/((molL^(-1))^(0))=molL^(-1)s^(-1)`
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