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The resonating structure of NO are repre...

The resonating structure of `NO` are represented by

A

`.overset(..)N=overset(..)underset(..)O:harr.overset(+)overset(..)N equiv overset(-)overset(..)O`

B

`:overset(.)N=overset(..)underset(..)Oharr:overset(-)overset(..)N=overset(+)overset(.)O:`

C

`N=overset(..)O:harr:N=overset(..)O`

D

`:N=O:harr:Nequivoverset(..)O`

Text Solution

Verified by Experts

The correct Answer is:
B

The structure of the molecules is a reasonance hybrid of the two forms:
`:overset(.)N=overset(..)O:harr:overset(-)overset(..)N=overset(+)overset(.)O:`
The bond length `N-O` is `115`pm, which is intermediate between a double and a triple bond.
Nitric oxide readily loses its unpaired electron from the antibonding orbital to form the nitrosyl ion `(NO^(+))`, which is diamagnetic and has a shorter`N-O` bond length `(106 p m)` then that of the parent molecules `(115 p m)`. This triple-bonded (bond order is `3`) ion is isoelectronic with `CO,` and `N_(2)`. It forms many analofous metal complexes.
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Knowledge Check

  • Resonating structures have same :

    A
    Atomic arrangements
    B
    Electronic arrangements
    C
    Total charge
    D
    Sigma bond
  • Number of resonance structure of

    A
    5
    B
    7
    C
    8
    D
    9
  • Resonating structures of a molecule have:

    A
    identical bonding
    B
    different bonding
    C
    identical arrangement of atoms and nearly same energies
    D
    tha same number of paired and unpaired electrons
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