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The resonating structure of NO are repre...

The resonating structure of `NO` are represented by

A

`.overset(..)N=overset(..)underset(..)O:harr.overset(+)overset(..)N equiv overset(-)overset(..)O`

B

`:overset(.)N=overset(..)underset(..)Oharr:overset(-)overset(..)N=overset(+)overset(.)O:`

C

`N=overset(..)O:harr:N=overset(..)O`

D

`:N=O:harr:Nequivoverset(..)O`

Text Solution

Verified by Experts

The correct Answer is:
B

The structure of the molecules is a reasonance hybrid of the two forms:
`:overset(.)N=overset(..)O:harr:overset(-)overset(..)N=overset(+)overset(.)O:`
The bond length `N-O` is `115`pm, which is intermediate between a double and a triple bond.
Nitric oxide readily loses its unpaired electron from the antibonding orbital to form the nitrosyl ion `(NO^(+))`, which is diamagnetic and has a shorter`N-O` bond length `(106 p m)` then that of the parent molecules `(115 p m)`. This triple-bonded (bond order is `3`) ion is isoelectronic with `CO,` and `N_(2)`. It forms many analofous metal complexes.
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R SHARMA-THE P BLOCK ELEMENTS-Follow-up Test 6
  1. Which of the following is wrong for nitrogen (I) oxide?

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  2. Nitrous oxide reacts with red -hot copper to give

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  3. Sodium azide (NaN(3))is prepared by heating a mixture of

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  4. In the N(2)Omolecule the

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  5. Nitric oxide(NO)is prepared in the laboratory by

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  6. Which of the following statement is incorrect for nitric oxide (NO)?

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  7. The number of valence electrons in nitric oxide is11. Among these,one ...

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  8. The resonating structure of NO are represented by

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  9. Which of the following complexes is responsible for the brown colour o...

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  10. Which of the following statement is correct regarding the nitric oxide...

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  11. Nitrogen sesquoxide (N(2)O(3))canbe obtained by cooling (below-30^(@)C...

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  12. Nitrogen sesquoxide (N(2)O(3) is a//an

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  13. NO(2) a red -brown poisonous gas is prepared in the laboratory by heat...

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  14. which of the following statement is not correct for the nitrogen dioxi...

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  15. In the formation of the dimer N(2)O(4)from two molecules of NO(2)the o...

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  16. NO(2) reacts with F(2) to give

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  17. Liquid N(2)O(4)is a useful nonaqueous solvent in which

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  18. Dinitrogen pentoxide ,a colourless deliquescentsolid is ,prepared by

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  19. Which of the following statement is correct?

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  20. Which of the following is incorrect for nitrogen pentoxide?

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