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Which of the following is the active spe...

Which of the following is the active species in the nitration of aromatic organic compounds ?

A

`NO_(3)^(-)`

B

`NO_(2)^(+)`

C

`NO^(+)`

D

`NO_(2)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
2

when nitric acid is mixed with concentrated sulphuric acid,the nitronium ion `NO_(2)^(+)` is formed. This is the active species in the nitration of aromatic organic compounds.
`HNO_(3)overset(+H^(+))underset(-H_(2)O)(rarr)NO_(2)^(+)`
This is the important step in making explosives ,or the nitro compounds may be reduced to aniline and used for making dyestuffs.
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