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which of the following statement is inco...

which of the following statement is incorrect regarding the chloride dioxide `(CIO_(2))` molecules?

A

The two `Cl-O` bond lengths are equal

B

Both `CI-O` bond lengths are longer than for single `Cl-O` bonds

C

Both `Cl-O` bond length are shorter than for single `Cl-O` bonds

D

`CIO_(2)`mioleculs is angular with` O-Cl-O` bond angle being `118^(@)`

Text Solution

Verified by Experts

The correct Answer is:
2

The chlorine-oxygen bond length is only `140` pm, much shorter than the 140 pm that is typical for a single bond length, and it is very close to that of a typical chlorine double bond. A possible electron dot structure reflecting this bond order is shown in figure:
`overset(..)underset(..)O::overset(..)underset(..)Cl::overset(..)underset(..)O` or `overset(..)underset(..)O=overset(.)underset(..)C=overset(..)underset(..)O`
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R SHARMA-THE P BLOCK ELEMENTS-QUESTION BANK
  1. Which of the following is the only exothermic oxide of chlorine?

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  2. Which of the following is not coloured?

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  3. which of the following statement is incorrect regarding the chloride d...

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  4. which of the following compouds of fluorine is used for dielectrics?

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  5. An aqueous solution of sodium carbonate absorbs NO and NO(2) to yield

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  6. which of the following quickely absorbs oxygen?

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  7. When orthophosphoric acid is heated to 600^(@)C the product formed is

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  8. Which of the following compounds is mixed with N(2)O(4) to serve as a ...

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  9. Reduction of hydrazine with zinc and HCI gives

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  10. Hydroxylamine (NH(2)OH) is manufacture in large quantities to make cyc...

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  11. Lithium reacts with hydrogen azide to produce

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  12. The azide ion is a resonance hybrid of "" structures

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  13. The hydrogen azide molecules has a bent geometery .The bond angle H-N-...

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  14. Which of the following is very similar to CO as a ligand?

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  15. Which of the following has lest covalent P-H bond ? .

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  16. Active nitrogen can be made by passing an electric spark through N(2) ...

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  17. Nitrolim is a mixtrue of

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  18. Ammonia on reaction with hyprochlorite ions can form

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  19. NO(2) is easily

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  20. Which of the following species has the least bond angle?

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