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Alky1 cyanides are reduced to primary am...

Alky1 cyanides are reduced to primary amines by

A

hydrogen and a catalyst

B

lithium aluminium hydride

C

sodiunm and ethanol

D

all of these

Text Solution

Verified by Experts

The correct Answer is:
D

Complete reduction of cyanides to primary amines can be achieved by any of these reducing agents
`R-CN overset([H])rarrR-CH_(2)NH_(2)`
Note that partial rduction of cyanides gives aldehydes.
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Knowledge Check

  • Aliphatic nitroalkanes are reduced to primary amines by .

    A
    catalytic hydrogenation
    B
    lithium aluminium hydride
    C
    metal in acid solution
    D
    all of these
  • Nitro alkanes are reduced to amines by

    A
    `Na//Hg`
    B
    `Na//`alcohol
    C
    `Sn//Hg`
    D
    `Sn//conc HCI`
  • Select the incorrect statement. I. Methyl cyanide is is reduced to methyl amine by LiAlH_4 II. Methyl isocyanide is hydrolysed to methyl amine III. Homologated 1@ amine is obtained in the process R – Br overset (NaCN) rarr overset (LiAlH_4) rarr

    A
    Only I
    B
    Only II
    C
    I and III
    D
    II and III
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    A: Secondary amines and phenols undergo Liebermann nitroso reaction. R: Secondary amines are move basic than primary amines.

    Ethyl cyanide (A) can be converted to ethyl amine (B) by:

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