Home
Class 12
CHEMISTRY
Aromatic nitriles (ArCN) are not prepare...

Aromatic nitriles `(ArCN)` are not prepared by reaction .

A

`ArX+KCN`

B

`ArN_(2)CI+CuCN`

C

`ArCONH_(2)+P_(2)O_(5)`

D

`ArCONH_(2)+SOCI_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Aryl halides , being inert toward nucleophilic aromatic substitution do not react with `KCN` under normal conditions
`C_(6)H_(5)CIunderset(heat)overset("CuCN in DMF")rarrC_(6)H_(5)CN`
`ArN_(2)Cioverset(CuCN)rarrArCN`(Sandmeyer's reaction)
`ArCONH_(2)underset(SOCI_(2))overset(P_(2)O_(5))rarrArCH+H_(2)O`(Dehydration) .
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

Propane nitrile can be prepared by heating ......

Butane nitrile can be prepared by heating

Butane nitrile can be prepared by heating

Why cannot be aromatic primary amines prepared by Gabriel phalimide synthesis ?

R SHARMA-AMINES-LevelII
  1. C(6)H(5)CONHCH(3) can be converted into C(6)H(5)CH(2)NHCH(3) by .

    Text Solution

    |

  2. Which of the following does not reduce Tollens reagent .

    Text Solution

    |

  3. Aromatic nitriles (ArCN) are not prepared by reaction .

    Text Solution

    |

  4. A nitrogen containingg organic compound gave an oily liguid on heating...

    Text Solution

    |

  5. C(6)H(5)NH(2)overset((CH(3)CO)(2)O)rarrXunderset(C CI(4))overset(Br(2)...

    Text Solution

    |

  6. Among the following the weakest base is .

    Text Solution

    |

  7. Nitrobenzene gives N-phenylhydroxylamine by

    Text Solution

    |

  8. Which is formed when (CH(3))NOH is heated?

    Text Solution

    |

  9. An organic compound (A) on reduction gives compound (B) which on treat...

    Text Solution

    |

  10. Which of the following compounds possesses two configurationally stabl...

    Text Solution

    |

  11. When stannous chloride and hydrochloric acid are used as the reducing ...

    Text Solution

    |

  12. The reation of RCONH(2) with a mixture of Br(2) and aqueous KOH gives ...

    Text Solution

    |

  13. Consider the following sequence of reactions The product t(C ) cont...

    Text Solution

    |

  14. Consider the following sequence of reactions The final product (B) is ...

    Text Solution

    |

  15. Consider the following sequence of reactions (CH(3))(2)CHCOOHunderse...

    Text Solution

    |

  16. Which of the following is least reactive toward complex formation with...

    Text Solution

    |

  17. The product formed in the reaction .

    Text Solution

    |

  18. Diazonium salts form phenylhydrazines when reduced with zinc and hyd...

    Text Solution

    |

  19. In the reaction shown below the major product (s) formed is/are .

    Text Solution

    |

  20. In the above reaction the product is

    Text Solution

    |