Home
Class 12
CHEMISTRY
Which one of following on reduction with...

Which one of following on reduction with lithium aluminium hydride yields a secondary amine ? .

A

Methy1 cyanide

B

Nitroethane

C

Methy1 isocyanide

D

Acetamide

Text Solution

Verified by Experts

The correct Answer is:
C
With `LiAIH_(4)` as well as on catalytic hydrogenation isocyanides arwe reduced to N-methylamines
`RNC overset(LAH)rarrRNHCH_(3)`
`underset("Methylisocyanide")(CH_(3bar)overset(+)N-=barC):overset(LAH)rarrCH_(3)underset("20 amine")(NHCH_(3))` .
Promotional Banner

Topper's Solved these Questions

  • AMINES

    R SHARMA|Exercise LevelII|53 Videos

  • ALCOHOL, PHENOL AND ETHERS

    R SHARMA|Exercise ETHERS level IV|7 Videos

  • BIOMOLECULES

    R SHARMA|Exercise Archives|47 Videos

Similar Questions

Explore conceptually related problems

Which of the following on reduction with lithium aluminium hydride yields a secondary amine ?

Propanoic acid on reduction with lithium aluminium hydride would give

Which one of the following compounds on reduction with LiAIH_(4) yeilds a secondary amine?

Lithium aluminium hydride LiAlH_(4) ,acts as

Compound 'A' is prepared by oxidation of compound 'B' with alkaline KMnO_(4) . Compound 'A' on reduction with lithium aluminium hydride gets converted back to compound 'B'. When compound 'A' is heated with compound 'B' in the presence of H_(2)SO_(4) , it produces fruity smell of compound 'C'. To which family, the compounds 'A', 'B' and 'C' belong to ?

R SHARMA-AMINES-Archives
  1. What is the product obtained in the following reaction

    Text Solution

    |

  2. In a reactione a coloured product C was obtained The structure of C wo...

    Text Solution

    |

  3. Which of the following statements about primary amines is false ? .

    Text Solution

    |

  4. Predict the product

    Text Solution

    |

  5. Nitrobenzenen can be prepared from benzene by using a mixture of conc ...

    Text Solution

    |

  6. In a reactione a coloured product C was obtained The structure of C wo...

    Text Solution

    |

  7. Which one of following on reduction with lithium aluminium hydride yie...

    Text Solution

    |

  8. Which of the following is more basic than aniline? .

    Text Solution

    |

  9. In a set of reactions propionic acid yielded a compound D CH(3)CH(2)...

    Text Solution

    |

  10. Aniline in a set of reactions yielded a product D C(6)H(5)NH(2)under...

    Text Solution

    |

  11. Electrolytic reduction of nitrobenzene in weakly acidic medium gives .

    Text Solution

    |

  12. Aniline when diazotiesd in cold and then treated with dimethy1 aniline...

    Text Solution

    |

  13. Compound C would be

    Text Solution

    |

  14. CH(3)CH(2)Cioverset(NaCN)rarrXoverset(Ni//H(2))rarrYunderset("anhydrid...

    Text Solution

    |

  15. The product 'P' in the above reactions is

    Text Solution

    |

  16. Intermediate formed during reaction of RCONH(2) with Br(2) and KOH are...

    Text Solution

    |

  17. Match the compounds given in List I with their characteristic reaction...

    Text Solution

    |

  18. An organic compound (A) on reduction gives compound (B) which on treat...

    Text Solution

    |

  19. Acetamide is treated separaately with the following reagents Which one...

    Text Solution

    |

  20. In a set of reaction m-bromobenzoic acid gives a product D. Identify t...

    Text Solution

    |