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Aniline in a set of reactions yielded a ...

Aniline in a set of reactions yielded a product `D`
`C_(6)H_(5)NH_(2)underset(HCI)overset(NaNO_(2))rarrAoverset(CuCN)rarrBunderset(Ni)overset(H_(2))rarrCoverset(HNO_(2))rarrD`
The structure of the product `D` would be .

A

`C_(6)H_(5)CH_(2)OH`

B

`C_(6)H_(5)CH_(2)NH_(2)`

C

`C_(6)H_(5)NHOH`

D

`C_(6)H_(5)NHCH_(2)CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A

Step(1) involves diazotisation step `(2)` is Sandmeyer reaction to yield cyanide step`(3)` involves reduction of cyanide to yield a `1^(@)` amine which reacts with nitrous acid to yield an alcohol

underset(Ni)overset(H_(2))(to) C_(6)H_(5)CH_(2)NH_(2) overset(NHO_(2))(to) C_(6)H_(5)CH_(2)OH`
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