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An organic compound (A) on reduction giv...

An organic compound `(A)` on reduction gives compound `(B)` which on treatment with `CHCI_(3)` and alcoholic `KOH` gives compound `(C )` which on hydrolysis gives aniline but on compound `(C )` which on hydrolysis gives aniline but on catalytic reduction gives n-methylaniline The compound `(A)` is .

A

nitrobenzene

B

nitromethane

C

Methylamine reacts with nitrous acid and liberates `N_(2)` from aqueous solution .

D

aniline

Text Solution

Verified by Experts

The correct Answer is:
A

Since N-methyl aniline is a `2^(@)` amine `C` must be an isocyanide which implies that `B` is `1^(@)` aromic amine and hence `A` is nitrobenzene
.
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R SHARMA-AMINES-Archives
  1. What is the product obtained in the following reaction

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  2. In a reactione a coloured product C was obtained The structure of C wo...

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  3. Which of the following statements about primary amines is false ? .

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  4. Predict the product

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  5. Nitrobenzenen can be prepared from benzene by using a mixture of conc ...

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  6. In a reactione a coloured product C was obtained The structure of C wo...

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  7. Which one of following on reduction with lithium aluminium hydride yie...

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  8. Which of the following is more basic than aniline? .

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  9. In a set of reactions propionic acid yielded a compound D CH(3)CH(2)...

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  10. Aniline in a set of reactions yielded a product D C(6)H(5)NH(2)under...

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  11. Electrolytic reduction of nitrobenzene in weakly acidic medium gives .

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  12. Aniline when diazotiesd in cold and then treated with dimethy1 aniline...

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  13. Compound C would be

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  14. CH(3)CH(2)Cioverset(NaCN)rarrXoverset(Ni//H(2))rarrYunderset("anhydrid...

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  15. The product 'P' in the above reactions is

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  16. Intermediate formed during reaction of RCONH(2) with Br(2) and KOH are...

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  17. Match the compounds given in List I with their characteristic reaction...

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