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Among the following, total no. of planar...

Among the following, total no. of planar species is :
(i) `SF_(4) " " (ii) BrF_(3) " " (iii) XeF_(2) " " (iv) IF_(5)`
(v)` SbF_(4)^(-) " " (vi) SF_(5)^(-) " " (vii) SeF_(3)^(+) " " (viii) CH_(3)^(+)`
(ix) `PCl_(4)^(+)`

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The correct Answer is:
To determine the total number of planar species among the given compounds and ions, we will follow these steps: ### Step 1: Identify the central atom and its valence electrons For each compound/ion, we will identify the central atom and count its valence electrons. 1. **SF₄**: Central atom is S (Sulfur), which has 6 valence electrons. 2. **BrF₃**: Central atom is Br (Bromine), which has 7 valence electrons. 3. **XeF₂**: Central atom is Xe (Xenon), which has 8 valence electrons. 4. **IF₅**: Central atom is I (Iodine), which has 7 valence electrons. 5. **SbF₄⁻**: Central atom is Sb (Antimony), which has 5 valence electrons plus 1 from the negative charge. 6. **SF₅⁻**: Central atom is S (Sulfur), which has 6 valence electrons plus 1 from the negative charge. 7. **SeF₃⁺**: Central atom is Se (Selenium), which has 6 valence electrons minus 1 from the positive charge. 8. **CH₃⁺**: Central atom is C (Carbon), which has 4 valence electrons minus 1 from the positive charge. 9. **PCl₄⁺**: Central atom is P (Phosphorus), which has 5 valence electrons plus 1 from the positive charge. ### Step 2: Calculate the hybridization Using the formula for hybridization: \[ \text{Hybridization} = \frac{1}{2} \left( \text{Number of valence electrons} + \text{Number of monovalent atoms} - \text{Positive charge} + \text{Negative charge} \right) \] 1. **SF₄**: \[ \text{Hybridization} = \frac{1}{2}(6 + 4 - 0) = 5 \rightarrow \text{sp}^3\text{d} \] 2. **BrF₃**: \[ \text{Hybridization} = \frac{1}{2}(7 + 3 - 0) = 5 \rightarrow \text{sp}^3\text{d} \] 3. **XeF₂**: \[ \text{Hybridization} = \frac{1}{2}(8 + 2 - 0) = 5 \rightarrow \text{sp}^3\text{d} \] 4. **IF₅**: \[ \text{Hybridization} = \frac{1}{2}(7 + 5 - 0) = 6 \rightarrow \text{sp}^3\text{d}^2 \] 5. **SbF₄⁻**: \[ \text{Hybridization} = \frac{1}{2}(5 + 4 + 1) = 5 \rightarrow \text{sp}^3\text{d} \] 6. **SF₅⁻**: \[ \text{Hybridization} = \frac{1}{2}(6 + 5 + 1) = 6 \rightarrow \text{sp}^3\text{d}^2 \] 7. **SeF₃⁺**: \[ \text{Hybridization} = \frac{1}{2}(6 + 3 - 1) = 4 \rightarrow \text{sp}^3 \] 8. **CH₃⁺**: \[ \text{Hybridization} = \frac{1}{2}(4 + 3 - 1) = 3 \rightarrow \text{sp}^2 \] 9. **PCl₄⁺**: \[ \text{Hybridization} = \frac{1}{2}(5 + 4 - 1) = 4 \rightarrow \text{sp}^3 \] ### Step 3: Determine the geometry and planarity - **SF₄**: Seesaw (not planar) - **BrF₃**: T-shaped (planar) - **XeF₂**: Linear (planar) - **IF₅**: Square pyramidal (not planar) - **SbF₄⁻**: Tetrahedral (not planar) - **SF₅⁻**: Square planar (planar) - **SeF₃⁺**: Trigonal pyramidal (not planar) - **CH₃⁺**: Trigonal planar (planar) - **PCl₄⁺**: Tetrahedral (not planar) ### Step 4: Count the planar species The planar species identified are: 1. BrF₃ 2. XeF₂ 3. SF₅⁻ 4. CH₃⁺ Thus, the total number of planar species is **4**. ### Final Answer: The total number of planar species is **4**. ---
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