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Consider the following compounds : (i)...

Consider the following compounds :
`(i) IF_(5) " " (ii) ClI_(4)^(-) " " (iii) XeO_(2)F_(2) " " (iv) NH_(2)^(-) `
`(v) BCl_(3) " " (vi) BeCl_(2) " " (vii) AsCl_(4)^(+) " " (viii) B(OH)_(3)`
(ix) `NO_(2)^(-) " " (x) ClO_(2)^(+)`
Then calculate value of "x+y-z", here, x,y and z are total number of compounds in given compounds in which central atom used their all three p-orbitals, only two p-orbitals and only one p-orbital in hybridisation respectively .

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The correct Answer is:
To solve the problem, we need to determine the hybridization of each compound and classify them based on the number of p-orbitals used in the hybridization. We will then calculate the values of x, y, and z, where: - x = number of compounds using all three p-orbitals - y = number of compounds using only two p-orbitals - z = number of compounds using only one p-orbital Let's analyze each compound step by step: ### Step 1: Calculate Hybridization for Each Compound 1. **IF₅** - Valence electrons of Iodine (I) = 7 - Monovalent atoms (F) = 5 - Charge = 0 - Hybridization = \( \frac{1}{2} (7 + 5 + 0) = \frac{12}{2} = 6 \) → **sp³d²** - **p-orbitals used = 5** 2. **ClI₄⁻** - Valence electrons of Chlorine (Cl) = 7 - Monovalent atoms (I) = 4 - Charge = +1 (due to negative charge) - Hybridization = \( \frac{1}{2} (7 + 4 + 1) = \frac{12}{2} = 6 \) → **sp³d²** - **p-orbitals used = 5** 3. **XeO₂F₂** - Valence electrons of Xenon (Xe) = 8 - Monovalent atoms (F) = 2 - Charge = 0 - Hybridization = \( \frac{1}{2} (8 + 2 + 0) = \frac{10}{2} = 5 \) → **sp³d** - **p-orbitals used = 4** 4. **NH₂⁻** - Valence electrons of Nitrogen (N) = 5 - Monovalent atoms (H) = 2 - Charge = +1 - Hybridization = \( \frac{1}{2} (5 + 2 + 1) = \frac{8}{2} = 4 \) → **sp³** - **p-orbitals used = 3** 5. **BCl₃** - Valence electrons of Boron (B) = 3 - Monovalent atoms (Cl) = 3 - Charge = 0 - Hybridization = \( \frac{1}{2} (3 + 3 + 0) = \frac{6}{2} = 3 \) → **sp²** - **p-orbitals used = 2** 6. **BeCl₂** - Valence electrons of Beryllium (Be) = 2 - Monovalent atoms (Cl) = 2 - Charge = 0 - Hybridization = \( \frac{1}{2} (2 + 2 + 0) = \frac{4}{2} = 2 \) → **sp** - **p-orbitals used = 1** 7. **AsCl₄⁺** - Valence electrons of Arsenic (As) = 5 - Monovalent atoms (Cl) = 4 - Charge = -1 (due to positive charge) - Hybridization = \( \frac{1}{2} (5 + 4 - 1) = \frac{8}{2} = 4 \) → **sp³** - **p-orbitals used = 3** 8. **B(OH)₃** - Valence electrons of Boron (B) = 3 - Monovalent atoms (OH) = 3 - Charge = 0 - Hybridization = \( \frac{1}{2} (3 + 3 + 0) = \frac{6}{2} = 3 \) → **sp²** - **p-orbitals used = 2** 9. **NO₂⁻** - Valence electrons of Nitrogen (N) = 5 - Monovalent atoms (O) = 2 - Charge = +1 - Hybridization = \( \frac{1}{2} (5 + 2 + 1) = \frac{8}{2} = 4 \) → **sp²** - **p-orbitals used = 2** 10. **ClO₂⁺** - Valence electrons of Chlorine (Cl) = 7 - Monovalent atoms (O) = 2 - Charge = -1 (due to positive charge) - Hybridization = \( \frac{1}{2} (7 + 2 - 1) = \frac{8}{2} = 4 \) → **sp²** - **p-orbitals used = 2** ### Step 2: Count the Number of Compounds for x, y, and z - **x (using all 3 p-orbitals)**: - IF₅, ClI₄⁻, XeO₂F₂, NH₂⁻, AsCl₄⁺ → **5 compounds** - **y (using only 2 p-orbitals)**: - BCl₃, B(OH)₃, NO₂⁻, ClO₂⁺ → **4 compounds** - **z (using only 1 p-orbital)**: - BeCl₂ → **1 compound** ### Step 3: Calculate x + y - z Now we can compute the final value: - \( x + y - z = 5 + 4 - 1 = 8 \) ### Final Answer The value of \( x + y - z \) is **8**. ---

To solve the problem, we need to determine the hybridization of each compound and classify them based on the number of p-orbitals used in the hybridization. We will then calculate the values of x, y, and z, where: - x = number of compounds using all three p-orbitals - y = number of compounds using only two p-orbitals - z = number of compounds using only one p-orbital Let's analyze each compound step by step: ...
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