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Consider the following species NO(3)^(-)...

Consider the following species `NO_(3)^(-), SO_(4)^(2-), ClO_(3)^(-),SO_(3), PO_(4)^(3-), XeO_(3),CO_(3)^(2-), SO_(3)^(2-)`
Then calculate value of |x-y|, where
x : Total number of species which have bond order 1.5 or greater than 1.5
y : Total number of species which have bond order less than 1.5

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The correct Answer is:
To solve the problem, we need to determine the bond order of each species listed and categorize them into two groups: those with a bond order of 1.5 or greater (x) and those with a bond order less than 1.5 (y). Finally, we will calculate |x - y|. ### Step-by-Step Solution: 1. **Identify the species and calculate their total valence electrons:** - **NO₃⁻**: N (5) + 3O (6) + 1 (for the negative charge) = 24 electrons - **SO₄²⁻**: S (6) + 4O (6) + 2 (for the negative charge) = 32 electrons - **ClO₃⁻**: Cl (7) + 3O (6) + 1 (for the negative charge) = 26 electrons - **SO₃**: S (6) + 3O (6) = 24 electrons - **PO₄³⁻**: P (5) + 4O (6) + 3 (for the negative charge) = 32 electrons - **XeO₃**: Xe (8) + 3O (6) = 26 electrons - **CO₃²⁻**: C (4) + 3O (6) + 2 (for the negative charge) = 24 electrons - **SO₃²⁻**: S (6) + 3O (6) + 2 (for the negative charge) = 26 electrons 2. **Draw the Lewis structures and calculate bond orders:** - **NO₃⁻**: Bond order = 4 bonds / 3 oxygen = 1.33 (y) - **SO₄²⁻**: Bond order = 6 bonds / 4 oxygen = 1.5 (x) - **ClO₃⁻**: Bond order = 5 bonds / 3 oxygen = 1.67 (x) - **SO₃**: Bond order = 6 bonds / 3 oxygen = 2 (x) - **PO₄³⁻**: Bond order = 5 bonds / 4 oxygen = 1.25 (y) - **XeO₃**: Bond order = 6 bonds / 3 oxygen = 2 (x) - **CO₃²⁻**: Bond order = 4 bonds / 3 oxygen = 1.33 (y) - **SO₃²⁻**: Bond order = 4 bonds / 3 oxygen = 1.33 (y) 3. **Count the number of species in each category:** - **x (bond order ≥ 1.5)**: SO₄²⁻, ClO₃⁻, SO₃, XeO₃ (4 species) - **y (bond order < 1.5)**: NO₃⁻, PO₄³⁻, CO₃²⁻, SO₃²⁻ (4 species) 4. **Calculate |x - y|:** - x = 4 - y = 4 - |x - y| = |4 - 4| = 0 ### Final Answer: The value of |x - y| is **0**.

To solve the problem, we need to determine the bond order of each species listed and categorize them into two groups: those with a bond order of 1.5 or greater (x) and those with a bond order less than 1.5 (y). Finally, we will calculate |x - y|. ### Step-by-Step Solution: 1. **Identify the species and calculate their total valence electrons:** - **NO₃⁻**: N (5) + 3O (6) + 1 (for the negative charge) = 24 electrons - **SO₄²⁻**: S (6) + 4O (6) + 2 (for the negative charge) = 32 electrons - **ClO₃⁻**: Cl (7) + 3O (6) + 1 (for the negative charge) = 26 electrons ...
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