Home
Class 12
CHEMISTRY
Select the correct code about complex [C...

Select the correct code about complex `[Cr(NO_(2))(NH_(3))_(5)][ZnCl_(4)] :`
`(I)` IUPAC name of compoun is pentaamminenitrito`-N-`chromium `(III)` tetrachlorozincate `(II)`
`(II)` It shows geometrical isomerism
`(III)` It shows linkage isomerism
`(IV)` It shows coordination isomerism`

A

III, IV

B

I, III, IV

C

II, III and IV

D

I, II, III and IV

Text Solution

Verified by Experts

The correct Answer is:
B
(I) IUPAC name is Pentaamminetrito-N-chromium(III) tetrachlorozincate
(II) It does not exhibit geometrical isomerism.
(III) it show linkage isomerism due to presence of ambidentate ligand `NO_(2)^(-)`
(IV) its coordination isomers are:
`[CrCl(NH_(3))_(5)][ZnCl_(3)(NO_(2))],[CrCl_(2)(NH_(3))_(4)][ZnCl_(2)(NO_(2))NH_(3)]`
`[Zn(NO_(2))(NH_(3))_(3)][CrCl_(4)(NH_(3))_(2)]`
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise LEVEL 3 (PASSAGE TYPE)|97 Videos

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise ASSERTION-REASON TYPE QUESTIONS|26 Videos

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise SUBJECTIVE PROBLEMS|43 Videos

  • CHEMICAL BONDING (BASIC)

    VK JAISWAL|Exercise Level 3 (Passive 11)|6 Videos

  • d-BLOCK ELEMENTS

    VK JAISWAL|Exercise SUBJECTIVE PROBLEMS|6 Videos

Similar Questions

Explore conceptually related problems

Select the correct code about complex [Cr(NO_(2))(NH_(3))_(5)][ZnCl_(4)] : (I) IUPAC name of compoun is pentaamminenitrito -N- chromium (III) tetrachlorozincate (II) (II) It shows geometrical isomerism (III) It shows likabe isomerism (IV) It shows coordination isomerism

The correct IUPAC name of the complex [Cr(NH_3)_5(NCS)][ZnCl_4] is

S-I: Ethene does not show geometrical isomerism. S-II: Alkenes can not show geometrical isomerism.

Explain the following: (i) Alkynes are acidic in nature (ii) Alkenes show geometrical isomerism

VK JAISWAL-CO-ORDINATION COMPOUNDS-LEVEL 1
  1. Which one of the following pairs of isomers ad ytpes of isomerism are ...

    Text Solution

    |

  2. The two compounds sulphato penta-ammine cobalt (III) bromide and sulph...

    Text Solution

    |

  3. Select the correct code about complex [Cr(NO(2))(NH(3))(5)][ZnCl(4)] :...

    Text Solution

    |

  4. A six coordination complex of formula CrCl(3)*6H(2)O has green colour....

    Text Solution

    |

  5. A complex has a composition corresponding to the formula CoBr(2)Cl.4NH...

    Text Solution

    |

  6. A mixture x containing 0.02 mol of [Co(NH(3))(5) SO(4)]Br and 0.02 mol...

    Text Solution

    |

  7. A complex of platinum, ammonia and chloride produces four ions per mol...

    Text Solution

    |

  8. The coordination number of a centrla metal atom in a complex is determ...

    Text Solution

    |

  9. Which statement about coordination number of a cation is true?

    Text Solution

    |

  10. In the Iso-electronic series of metal carbonyls, the C-O bond strength...

    Text Solution

    |

  11. Which is not true about metal carbonyls?

    Text Solution

    |

  12. There are four complexes of Ni. Select the complex(es) which will be a...

    Text Solution

    |

  13. Which of the following complex is an outer orbital complex?

    Text Solution

    |

  14. Which of the following complex is an outer orbital complex?

    Text Solution

    |

  15. The magnetic moment of [MnX(4)]^(2-) is 5.9 BM. The geometry of the co...

    Text Solution

    |

  16. The geometry of [Ni(CO)(4)] and [NiCl(2)(PPh(3))(2)] are :

    Text Solution

    |

  17. [Fe(H(2)O)(6)]^(2+) and [Fe(CN)(6)]^(4-)differ in :

    Text Solution

    |

  18. Which of the following order is correct in spectrochemical series of l...

    Text Solution

    |

  19. The species with spin only magnetic moment of sqrt(24) BM is:

    Text Solution

    |

  20. For the complexes showing the square pyramidal structure, the d-orbita...

    Text Solution

    |