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Complex compounds(s) which is optical ac...

Complex compounds(s) which is optical active and does ot dpeend upon the orientation of the ligands around metal cation:
(i) `[CoCl_(3)(NH_(3))_(3)]`
(ii) `[Co(en)_(3)]Cl_(3)`
(iii) `[Co(C_(2)O_(4))_(2)(NH_(3))_(2)]^(-)`
(iv) `[CrCl_(2)(NH_(3))_(2)(en)]^(+)`

A

(ii), (iii) and (iv)

B

(i), (ii) and (iv)

C

(ii) and (iv)

D

only (ii)

Text Solution

Verified by Experts

The correct Answer is:
A


Hence, orientation of ligands determine asymmetric nature of the complex.
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Which of the following can exhibit geometrical isomerism ? (i) [Co(NH_(3))_(4)Cl_(2)] (ii) [Co("en")_(3)]Cl_(2) (iii) [Co("en")_(2)(NO_(2))Cl] SCN (iv) [Co(NH_(3))_(6)][Cr(CN)_(6)]

Which of the following will have three stereoisomeric forms? (i) [Cr(NO_(3))_(3)(NH_(3))_(3)] (ii) K_(3)[Co(C_(2)O_(4))_(3)] (iii) K_(3)[CoCl_(2)(C_(2)O_(4))_(2)] (iv) [CoBrCl(en)_(2)]

Draw all the isomers (geometrical and optical) of: (i) [CoCl_(2)(en)_(2)]^(+) (ii) [Co(NH_(3))Cl(en)_(2)]^(2+) (iii) [Co(NH_(3))_(2)Cl_(2)(en)]^(+)

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