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[CoCl(2)(NH(3))(4)]^(+)+Cl^(-) to [CoCl(...

`[CoCl_(2)(NH_(3))_(4)]^(+)+Cl^(-) to [CoCl_(3)(NH_(3))_(3)]+NH_(3)`. If in this reaction two isomers of the produt are obtained, which is true for the iniital (reactant) complex:

A

compound is in cis-form

B

compound is in trans-form

C

compound is in both (cis and trans)

D

can't be predicted

Text Solution

Verified by Experts

The correct Answer is:
A
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[CoCl(NH_(3))_(5)]^(2+) is

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In the reaction [CoCI_(2)(NH_(3))_(4)]^(o+)rarr[CoCI_(3)(NH_(3))_(3)]+NH_(3) , only one isomer of the complex product is obtained Is the initial complex cis or trans ? .

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Consider the following reaction and statements: [Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_(3)]+NH_(3) Two isomers are produced if the reactant complex ion is a cis-isomer Two isomers are produced if the reactant complex ion is a trans-isomer Only one isomer is produced if the reactant complex ion is a trans-isomer Only one isomer is produced if the reactant complex ion is a cis – isomer The correct statements are

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  3. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  4. These questions consist of two statements each, printed as Assertion a...

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  5. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  6. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  7. STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optic...

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  8. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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  9. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

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  10. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

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  11. Assertion: Transition metal ion forming octahedral complexes undergo s...

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  12. Assertion: Complex ion [Co(NH(3))(6)]^(2+) is readily oxidized to [Co(...

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  13. Assertion: Hydrazine is a neutral ligand. Reason: It has two N as do...

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  14. Reason: Complex anion [Re(2)Cl(8)]^(2-) has one delta-bond, one sigma ...

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  15. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  16. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  17. Assertion: [Ti(H(2)O)(6)]^(4+) is coloured while [Sc(H(2)O)(6)]^(3+) i...

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  18. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  19. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  20. Assertion: Tetrahedral complexes with chiral structure exhibit optical...

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  21. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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