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Which of the following compound show opt...

Which of the following compound show optical isomerism?

A

cis-`[CrCl_(3)(NH_(3))_(3)]`

B

cis-`[Co(NH_(3))_(4)Cl_(2)]^(+)`

C

`[Co(en)_(3)]^(3+)`

D

trans-`[Co(en)_(2)Cl_(2)]^(+)`

Text Solution

Verified by Experts

The correct Answer is:
B

Compound `[Co(en)_(3)]^(3+)` can show optical isomerism.
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Which of the following compounds show optical isomerism? I. cis -[Co(NH_(3))_(4) Cl_(2)]^(+) II. Trans - [Co(en)_(2) Cl_(2)]^(+) III. Cis - [Co(en)_(2) cl_(2)]^(+) IV. [Co(en)_(3)]^(3+) Choose the correct answer form the codes given below.

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VK JAISWAL-CO-ORDINATION COMPOUNDS-ASSERTION-REASON TYPE QUESTIONS
  1. Which of the following compound show optical isomerism?

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  2. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  3. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  4. These questions consist of two statements each, printed as Assertion a...

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  5. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  6. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  7. STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optic...

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  8. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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  9. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

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  10. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

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  11. Assertion: Transition metal ion forming octahedral complexes undergo s...

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  12. Assertion: Complex ion [Co(NH(3))(6)]^(2+) is readily oxidized to [Co(...

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  13. Assertion: Hydrazine is a neutral ligand. Reason: It has two N as do...

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  14. Reason: Complex anion [Re(2)Cl(8)]^(2-) has one delta-bond, one sigma ...

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  15. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  16. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  17. Assertion: [Ti(H(2)O)(6)]^(4+) is coloured while [Sc(H(2)O)(6)]^(3+) i...

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  18. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  19. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  20. Assertion: Tetrahedral complexes with chiral structure exhibit optical...

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  21. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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