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Consider the following reactions of comp...

Consider the following reactions of complex compounds A,B and C
(i) `CoCl_(2)Br*5NH_(3) +excess" "Ag^(+)(aq)to1AgCl(s)`
(ii) `underset("Compound B")(CoCl_(2)Br*5NH_(3))+"excess "Ag^(+)(aq) to 2AgCl(s)`
(iii) `underset("Compound C")(CoCl_(2)Br*4NH_3)+"excess "Ag^(+)(aq.) to 1AgCl(s)`
Then according to the given information the correct statement(s) is/are:

A

Compounds(A) and (B) are ionisation isomers

B

Molar conductivity of compounds (A) and (B) are almost same

C

Compounds (A), (B) and (C) do not exhibit geometrical isomerism

D

Order of CFSE values, `Delta_(0)(A) gt Delta_(0)(B) gt Delta_(0)(C)`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

A:`[CoCl(NH_(3))_(5)]*BrCl`
`B:[CoBr(NH_(3))_(5)]*Cl_(2)`
`C:[CoBrCl(NH_(3))_(4)]*Cl`
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