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Which of the following is correct about ...

Which of the following is correct about Tetraamminedithiocyanato-s cobalt(III) tris(oxalato)cobaltate(III)?

A

Formula of the complex is `[Co(SCN)_(2)(NH_(3))_(4)][Co(o x)_(3)]`

B

It is a chelating complex and show linkage isomerism

C

it shows optical isomerism

D

it shows geometrical isomerism

Text Solution

Verified by Experts

The correct Answer is:
B, C, D
Formula of the complex `[Co^(III)(SCN_(2))(NH_(3))_(4)]_(3)[Co^(III)(o x)_(3)]`
Linkage isomerism is due to presence of `SCN^(-)`
optical isomerism is exhibited due to presence of `[Co(o x)_(3)]^(3-)` complex ion, which has asymmetric structure.
Geometrical isomerism is exhibited due to cationic part:
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