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The reagent one would choose to transfor...

The reagent one would choose to transform `CH_(3)CH_(2)COCl` into `CH_(3)CH_(2)COCH_(3)` is _______.

A

`CH_(3)Mgl`

B

`(CH_(3))_(2)Cd`

C

`(CH_(3)O)_(2)Mg`

D

`CH_(3)Cl`

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AI Generated Solution

The correct Answer is:
To transform `CH3CH2COCl` (an acid chloride) into `CH3CH2COCH3` (a ketone), we can follow these steps: ### Step 1: Identify the Reaction We need to convert an acid chloride to a ketone. The general reaction involves the addition of a nucleophile to the carbonyl carbon of the acid chloride. ### Step 2: Choose the Nucleophile The nucleophile we will use is an organocadmium reagent, specifically `CH3CdR` (where R is another alkyl group). In this case, we can use `CH3Cd(CH3)` which is an organocadmium reagent. ### Step 3: Mechanism of Reaction 1. The nucleophile (`CH3-` from the organocadmium reagent) will attack the carbonyl carbon of the acid chloride (`CH3CH2COCl`). 2. This results in the formation of a tetrahedral intermediate. 3. The chlorine atom (a good leaving group) will leave, resulting in the formation of the ketone `CH3CH2COCH3`. ### Step 4: Final Product After the reaction, we will have `CH3CH2COCH3`, which is the desired ketone. ### Conclusion The reagent that we would choose to transform `CH3CH2COCl` into `CH3CH2COCH3` is `CH3Cd(CH3)` (organocadmium reagent). ### Answer The reagent one would choose to transform `CH3CH2COCl` into `CH3CH2COCH3` is **organocadmium reagent**. ---
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TARGET PUBLICATION-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-CRITICAL THINKING
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