Identify the correct statement

Options

A. Aldehydes on reduction gives secondary alcohols
B. Ketones on reduction gives primary alcohols
C. Ketones reduce Fehling's solution and give red cuprous oxide
D. Ketones do not react with alcohols

Explanation

To identify the correct statement regarding aldehydes and ketones, let's analyze the provided information step by step.

### Step 1: Understand the Reduction of Aldehydes
- Aldehydes (RCHO) can be reduced to primary alcohols (RCH2OH).
- Therefore, the statement "Aldehyde on reduction gives secondary alcohol" is incorrect.

### Step 2: Understand the Reduction of Ketones
- Ketones (RC(=O)R') can be reduced to secondary alcohols (RCH(OH)R').
- Thus, the statement "Ketones on reduction gives primary alcohol" is incorrect.

### Step 3: Analyze the Reaction of Ketones with Fehling's Solution
- Ketones do not react with Fehling's solution, which is used to test for reducing sugars and aldehydes.
- The statement "Ketones reduce Fehling solution" is incorrect.

### Step 4: Review the Reaction of Aldehydes and Ketones with Alcohols
- Aldehydes can react with alcohols to form hemiacetals and acetals.
- Ketones can also react with alcohols to form similar products.
- The statement "Ketones do not react with alcohols" is misleading; they do react, but the rate may differ compared to aldehydes.

### Conclusion
Based on the analysis:
1. Aldehydes reduce to primary alcohols.
2. Ketones reduce to secondary alcohols.
3. Ketones do not react with Fehling's solution.
4. Both aldehydes and ketones can react with alcohols.

The correct statements are:
- Aldehydes give primary alcohols upon reduction.
- Ketones give secondary alcohols upon reduction.

### Final Answer
The correct statement is: "Aldehydes give primary alcohols and ketones give secondary alcohols upon reduction."

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