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In the Cannizzaro reaction given below: ...

In the Cannizzaro reaction given below:
`2Ph-CHO overset(overset(Θ)OH)rarrPh-CH_(2)OH+PhCO_(2)^(-)` the slowest step is:

A

The attack of OH at the carbonyl group

B

The transfer of hydride to the carbonyl group

C

The abstraction of proton from the carboxylic group

D

The deprotonation of `Ph-CH_(2)OH`

Text Solution

Verified by Experts

The correct Answer is:
B

In the Cannizaro's reaction given below
`2Ph-CHO overset(-OH)rarr Ph-CH_(2)OH+PhCOO^(-)`
The slowest step is transfer of hydride ion to the carbonyl group of second mole of aldehyde. Hence it is represented in following reaction mechanism.
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