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Aniline reacts with mixed acid (conc. HN...

Aniline reacts with mixed acid (conc. `HNO_(3)` and conc. `H_(2)SO_(4)`) at 288K to give `P(51%),Q(47%)` and R (2%). The major product(s) of the following reaction sequence is (are)

A

B

C

D

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The correct Answer is:
D
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Aniline reacts with mixed acid conc. HNO_(3) and conc. H_(2)SO_(4) at 288 K to give P (51 %), Q (47%) and R (2%). The major product(s) of the following reaction sequence is (are)

Mixture of conc. HNO_(3) and conc. H_(2)SO_(4) is known as

Knowledge Check

  • Aniline reacts with mixed acid (conc. HNO_(3) and conc. H_(2)SO_(4) ) at 288 K to give P (51%), Q (47%) and R(2%). The major product (s) of the following reaction sequence is (are)

    A
    B
    C
    D

  • Aniline reacts with mixed acid (cone. HNO_(3) and cone. H_(2)SO_(4) ) at 288 K to give P (51%), Q (47%) and R (2%) . The major product(s) the following reaction sequence is (are) : R underset({:((3)H_(3)O^(+)),((4)NaNO_(2)","HCl//273-278K),((5)EtOH","Delta):})overset({:((1)Ac_(2)O", pyridine"),((2)Br_(2)","CH_(3)CO_(2)H):})toS underset({:((3) NaNO_(2)","HCl//273-278K),((4)H_(3)PO_(2)):})overset({:((1)Sn//HCl),((2)Br_(2)//H_(2)O" (excess)"):})to major product(s)

    A
    B
    C
    D

  • Anisole with conc. HNO_(3) and conc. H_(2)SO_(4) gives

    A
    Phenol
    B
    Nitrobenzene
    C
    O - and - P - Nitroanisole
    D
    O- Nitroanisole

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