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For the reaction A + 2B to C, the ...

For the reaction ` A + 2B to ` C, the reaction rate is doubled if the concentration of A is doubled , the rate is increased by four times when concentrations of both A and B are increased by four times . The order of the reaction is _______.

A

3

B

0

C

1

D

2

Text Solution

Verified by Experts

The correct Answer is:
C

Rate, `r = k [A]^(a)[B]^(b)" "…(i)`
`2r = [2 A]^(a) [B]^(b)" "…(ii)`
`4r = [ 4 A ]^(a) [ 4 B]^(b) " "…(iii)`
Divding eqn. (ii) by eqn. (i), `2 = 2^(a) therefore a = 1`
Divding eqn. (ii) by eqn. (i)
`4 = 4^(a) 4^(b) = 4 xx 4^(b) = 4^(b+1)`
`therefore b + 1 = 1 or b = 0`
Hence, overall order = 1.
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