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Assertion. Order of a reaction can be fr...

Assertion. Order of a reaction can be fractional but molecularity is never fractional.
Reason. Order of reaction does not depend upon the stoichiometric coefficients of the balanced equation.

A

If both assertion and reason are true and reason is the true explanation of the assertion.

B

If both assertion and reason ae true but reason is not the true explanation of the assertion.

C

If assertion is true, but reason is false.

D

If both assertion and reason are false.

Text Solution

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The correct Answer is:
To solve the assertion and reason question regarding the order of a reaction and molecularity, we can follow these steps: ### Step 1: Understand the Definitions - **Order of a Reaction**: The order of a reaction is the sum of the powers of the concentration terms in the rate law expression. It can be determined experimentally and can take fractional values. - **Molecularity**: Molecularity refers to the number of reactant molecules involved in an elementary reaction. It is always a whole number (1, 2, 3, etc.) and cannot be fractional. ### Step 2: Analyze the Assertion - The assertion states that "the order of a reaction can be fractional but molecularity is never fractional." This is true. The order of a reaction can be determined from experimental data and can indeed be fractional, whereas molecularity, which is based on the number of molecules reacting, must be a whole number. ### Step 3: Analyze the Reason - The reason states that "the order of reaction does not depend upon the stoichiometric coefficients of the balanced equation." This is also true. The order of a reaction is derived from experimental observations and may not directly correlate with the stoichiometric coefficients in the balanced equation. ### Step 4: Conclusion - Since both the assertion and reason are true, and the reason correctly explains the assertion, we can conclude that the statement is correct. ### Final Answer - The assertion is true, and the reason is true, and the reason is the correct explanation for the assertion. ---

To solve the assertion and reason question regarding the order of a reaction and molecularity, we can follow these steps: ### Step 1: Understand the Definitions - **Order of a Reaction**: The order of a reaction is the sum of the powers of the concentration terms in the rate law expression. It can be determined experimentally and can take fractional values. - **Molecularity**: Molecularity refers to the number of reactant molecules involved in an elementary reaction. It is always a whole number (1, 2, 3, etc.) and cannot be fractional. ### Step 2: Analyze the Assertion - The assertion states that "the order of a reaction can be fractional but molecularity is never fractional." This is true. The order of a reaction can be determined from experimental data and can indeed be fractional, whereas molecularity, which is based on the number of molecules reacting, must be a whole number. ...
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